Ethylene → HCID 22601781, compound

HRID 2308353Notes

Reaction equation

HRID 2308353 reaction equation
Br[C:2]1[CH:3]=[C:4]([CH2:8][C:9]([O:11][CH3:12])=[O:10])[CH:5]=[CH:6][CH:7]=1.[CH2:13]=[CH2:14]>>[CH:13]([C:2]1[CH:3]=[C:4]([CH2:8][C:9]([O:11][CH3:12])=[O:10])[CH:5]=[CH:6][CH:7]=1)=[CH2:14]

Participants

3

Reactant 2

HCID 6325EthyleneHCID 11746402Methyl 2-(3-bromophenyl)acetate

Product 1

HCID 22601781HCID 22601781, compound

Procedure

Methyl 3-bromophenylacetate (8.0 g, 34.9 mmol) was reacted with ethylene using the procedure described in Example 6, step 1. The crude reaction product was purified by column chromatography (SiO2, 5% EtOAc in petroleum ether) to give 3,3′-bis-[(carbo-methoxy)methyl]stilbene and methyl 3-(ethenyl)phenyl-acetate as a white solid mixture.

Workup

  1. customThe crude reaction product
  2. customwas purified by column chromatography (SiO2, 5% EtOAc in petroleum ether)

Sources & evidence

ORD record
ord-cd3e82fb4f8049398d6dcdaec2576658
Source dataset
uspto-grants-2004_12
Patent number
US06835753B2

Reaction notes

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