Fluorine → HCID 12994024, compound

HRID 2308417Notes

Reaction equation

HRID 2308417 reaction equation
[C:1]([C:5]([C:8]([C:11]([C:14]([C:17]([C:20](C(F)=O)([F:22])[F:21])([F:19])[F:18])([F:16])[F:15])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])([F:4])([F:3])[F:2].FF.[C:28]([O:32][C:33]([C:36]([Cl:39])([F:38])[F:37])([Cl:35])[F:34])([F:31])([F:30])F>>[C:1]([C:5]([C:8]([C:11]([C:14]([C:17]([C:20]([C:28]([O:32][C:33]([C:36]([Cl:39])([F:37])[F:38])([Cl:35])[F:34])([F:30])[F:31])([F:22])[F:21])([F:18])[F:19])([F:16])[F:15])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])([F:4])([F:3])[F:2]

Participants

4

Reactant 3

HCID 24524FluorineHCID 67634Octanoyl fluoride, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-HCID 1027911,2-Dichloro-1,1,2-trifluoro-2-(trifluoromethoxy)ethane

Product 1

HCID 12994024HCID 12994024, compound

Procedure

19.65 g of CF3—OCFCl—CF2Cl as solvent, 23.07 g of CFCl═C—FCl (CFC 1112) and 7.57 g of CF3—(CF2)6—COF are introduced into the equipment described in the Example 1. The reaction mixture is maintained at the temperature of −55° C. and 1.5 Nl/h of fluorine diluted with nitrogen (molar ratio fluorine/nitrogen 1/5) are fed therein for 110 minutes.

Workup

  1. additiondiluted with nitrogen (molar ratio fluorine/nitrogen 1/5)

Sources & evidence

ORD record
ord-a61d3ca5930a493e97e19c10bca479f2
Source dataset
uspto-grants-2004_12
Patent number
US06835856B2

Reaction notes

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