HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → HCID 53645761, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | 1-[3-(Acetylthio)-2-(methoxycarbonylmethyl)propanoyl]-L-proline | HCID 54112383 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Solvent | Methanol | HCID 887 | — |
| Solvent | Sodium Hydroxide | HCID 14798 | — |
| Product | HCID 53645761 | HCID 53645761 | — |
Reaction Steps
To a solution of the product from Example 81 (3.0 g.) in methanol (60 ml.), 1N sodium hydroxide (60 ml.) is added. After 4 hours, the solution is applied to a column of Dowex 50 ion exchange resin in the hydrogen cycle, and the desired material is eluted with water to yield 2.3 g. of the named product Rf 0.2 (silica gel-benzene:acetic acid, 75:25).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04692458 |
| Source dataset | uspto-grants-1987_09 |
| ORD ID | ord-010af2fe034241aba9f66a6f575b2ba6 |
| Source note | uspto-grants-1987_09 |