Hydrochloric Acid → HCID 14047793, compound

HRID 2309122Notes

Reaction equation

HRID 2309122 reaction equation
O[CH2:2][N:3]1[CH2:7][CH2:6][N:5]([CH2:8]O)[C:4]1=[O:10].[C:11]([C:15]1[CH:16]=[C:17]([SH:26])[CH:18]=[C:19]([C:22]([CH3:25])([CH3:24])[CH3:23])[C:20]=1[OH:21])([CH3:14])([CH3:13])[CH3:12].Cl>CO>[C:11]([C:15]1[CH:16]=[C:17]([S:26][CH2:2][N:3]2[CH2:7][CH2:6][N:5]([CH2:8][S:26][C:17]3[CH:16]=[C:15]([C:11]([CH3:12])([CH3:13])[CH3:14])[C:20]([OH:21])=[C:19]([C:22]([CH3:25])([CH3:24])[CH3:23])[CH:18]=3)[C:4]2=[O:10])[CH:18]=[C:19]([C:22]([CH3:25])([CH3:24])[CH3:23])[C:20]=1[OH:21])([CH3:14])([CH3:13])[CH3:12]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 87042-Imidazolidinone, 1,3-bis(hydroxymethyl)-HCID 703702,6-Di-tert-butyl-4-mercaptophenol

Product 1

HCID 14047793HCID 14047793, compoundYield 78%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A solution of 3.65 grams of 1,3-bis(hydroxymethyl)-2-imidazolidone and 11.92 grams of 3,5-di-t-butyl-4-hydroxybenzenethiol in 100 ml of methyl alcohol was treated with anhydrous hydrogen chloride. The reaction mixture was cooled and the product recrystallized from methyl alcohol to give 11.43 grams of white solid, m.p. 173°-176° C.

Workup

  1. temperatureThe reaction mixture was cooled
  2. customthe product recrystallized from methyl alcohol

Sources & evidence

ORD record
ord-107f87cfea8e4cf28eb03959d9765b96
Source dataset
uspto-grants-1987_09
Patent number
US04692532

Reaction notes

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