N-Methoxy-1-phenylmethanimine → Benzyl(methoxy)amine

HRID 2309756Notes

Reaction equation

HRID 2309756 reaction equation
[CH3:1][O:2][N:3]=[CH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.C([BH3-])#N.[Na+]>CO>[CH3:1][O:2][NH:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1

Participants

4

Reactant 2

HCID 520653N-Methoxy-1-phenylmethanimineHCID 5003444Sodium cyanoborohydride

Product 1

HCID 11815413Benzyl(methoxy)amine

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

The procedure of Example VI is repeated using 15.0 g of O-methylbenzaldoxime, and 20.0 g of sodium cyanoborohydride in 100 ml of methanol. Bulb to bulb distillation of the crude product affords the title compound as a colorless liquid.

Workup

  1. distillationBulb to bulb distillation of the crude product

Sources & evidence

ORD record
ord-2d189d21640e4c2399cbcdf309e20537
Source dataset
uspto-grants-1987_09
Patent number
US04696964

Reaction notes

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