Acetic Acid → HCID 14498242, compound

HRID 231260Notes

Reaction equation

HRID 231260 reaction equation
C(O)(=O)C.[S:5]([O-:9])(=[O:8])(=[O:7])[CH3:6].C([O:17][CH:18]([CH2:30][O:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])[CH2:19][S:20]([CH2:23][CH2:24][CH2:25][N+:26]([CH3:29])([CH3:28])[CH3:27])(=[O:22])=[O:21])C1C=CC=CC=1>[C].[Pd].O>[S:5]([O-:9])(=[O:8])(=[O:7])[CH3:6].[OH:17][CH:18]([CH2:30][O:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])[CH2:19][S:20]([CH2:23][CH2:24][CH2:25][N+:26]([CH3:27])([CH3:29])[CH3:28])(=[O:22])=[O:21]

Participants

5

Reactant 2

HCID 176Acetic AcidHCID 20034841HCID 20034841, compound

Product 1

HCID 14498242HCID 14498242, compoundYield 88.1%

Reagents, catalysts & solvents 2

HCID 178418390HCID 178418390, compoundCatalystHCID 962WaterSolvent

Procedure

Into a mixed solvent consisting of 50 ml of acetic acid and 5 ml of water is dissolved 1.4 g of 3-[(2-benzyloxy-3-octadecyloxypropyl)sulfonyl]propyltrimethylammonium mesylate and the solution is shaked in the presence of palladiumcarbon under hydrogen streams. The catalyst is then removed by filtration and the filtrate is concentrated. The resulting residue is treated with acetone to give 1.07 g of the captioned compound as powder.

Workup

  1. customThe catalyst is then removed by filtration
  2. concentrationthe filtrate is concentrated
  3. additionThe resulting residue is treated with acetone

Sources & evidence

ORD record
ord-fa87d11330624a8fbf433ad2dfabeac3
Source dataset
uspto-grants-1989_07
Patent number
US04845219

Reaction notes

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