Trimethylamine → HCID 14498262, compound

HRID 231279Notes

Reaction equation

HRID 231279 reaction equation
[CH3:1][O:2][CH:3]([CH2:16][O:17][CH2:18][CH2:19][CH:20]([CH3:37])[CH2:21][CH2:22][CH2:23][CH:24]([CH3:36])[CH2:25][CH2:26][CH2:27][CH:28]([CH3:35])[CH2:29][CH2:30][CH2:31][CH:32]([CH3:34])[CH3:33])[CH2:4][S:5]([CH2:8][CH2:9][CH2:10][O:11][S:12]([CH3:15])(=[O:14])=[O:13])(=[O:7])=[O:6].[CH3:38][N:39]([CH3:41])[CH3:40]>C1(C)C=CC=CC=1>[S:12]([O-:14])(=[O:13])(=[O:11])[CH3:15].[CH3:1][O:2][CH:3]([CH2:16][O:17][CH2:18][CH2:19][CH:20]([CH3:37])[CH2:21][CH2:22][CH2:23][CH:24]([CH3:36])[CH2:25][CH2:26][CH2:27][CH:28]([CH3:35])[CH2:29][CH2:30][CH2:31][CH:32]([CH3:34])[CH3:33])[CH2:4][S:5]([CH2:8][CH2:9][CH2:10][N+:39]([CH3:41])([CH3:40])[CH3:38])(=[O:7])=[O:6]

Participants

4

Reactant 2

HCID 1146TrimethylamineHCID 20034840HCID 20034840, compound

Product 1

HCID 14498262HCID 14498262, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

In 20 ml of toluene containing 4 g of trimethylamine is dissolved 3.1 g of 3-mesyloxypropyl 2-methoxy-3-(3,7,11,15-tetramethylhexadecyloxy)propyl sulfone, and the mixture is stirred at room temperature for 3 days. The reaction mixture is concentrated under reduced pressures to leave a residue which in turn is purified by silica gel column chromatography to yield 2.49 g of the captioned compound.

Workup

  1. concentrationThe reaction mixture is concentrated under reduced pressures
  2. customto leave a residue which in turn
  3. customis purified by silica gel column chromatography

Sources & evidence

ORD record
ord-34b3b050fbf64431bc3c1d3f4a4673fd
Source dataset
uspto-grants-1989_07
Patent number
US04845219

Reaction notes

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