Dimethylformamide → (1-Methoxyethyl)(trimethyl)silane

HRID 2312814Notes

Reaction equation

HRID 2312814 reaction equation
[C:38]([CH3:39])([CH3:40])([CH3:41])[O:42][C:43]([CH2:44][Br:45])=[O:46].[C:47](=[O:48])([O-:49])[O-:50].[CH3:1][O:2][CH:3]([CH3:4])[Si:5]([CH3:6])([CH3:7])[CH3:8].[CH3:53][N:54]([CH3:55])[CH:56]=[O:57].[Cl:9][c:10]1[cH:11][cH:12][c:13]2[c:17]([cH:18]1)[NH:16][C:15](=[O:19])[C:14]21[CH:20]([C:33](=[CH:34][CH3:35])[CH2:36][CH3:37])[NH:21][C:22](=[O:32])[CH2:23][CH:24]1[c:25]1[cH:26][c:27]([Cl:31])[cH:28][cH:29][cH:30]1.[Cs+:51].[Cs+:52]>>[CH3:1][O:2][CH:3]([CH3:4])[Si:5]([CH3:6])([CH3:7])[CH3:8].[Cl:9][c:10]1[cH:11][cH:12][c:13]2[c:17]([cH:18]1)[NH:16][C:15](=[O:19])[C:14]21[CH:20]([C:33](=[CH:34][CH3:35])[CH2:36][CH3:37])[N:21]([CH2:44][C:43]([O:42][C:38]([CH3:39])([CH3:40])[CH3:41])=[O:46])[C:22](=[O:32])[CH2:23][CH:24]1[c:25]1[cH:26][c:27]([Cl:31])[cH:28][cH:29][cH:30]1

Participants

8

Reactant 6

HCID 6228DimethylformamideHCID 19660Carbonate IonHCID 79177tert-Butyl bromoacetateHCID 104967Cesium cation2×HCID 22400412(1-Methoxyethyl)(trimethyl)silaneHCID 74370458HCID 74370458, compound

Product 2

HCID 22400412(1-Methoxyethyl)(trimethyl)silaneHCID 77579611HCID 77579611, compound

Sources & evidence

ORD record
ord-f9346cc5ec7e4488ad8a9df1d8f5dad1
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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