Chlorine → HCID 14047294, compound

HRID 231914Notes

Reaction equation

HRID 231914 reaction equation
[Cl:1]Cl.ClC(SS[C:9]([O:30][CH2:31][C:32]([F:39])([N+:36]([O-:38])=[O:37])[N+:33]([O-:35])=[O:34])([O:20][CH2:21][C:22]([N+:27]([O-:29])=[O:28])([N+:24]([O-:26])=[O:25])[F:23])[O:10][CH2:11][C:12]([N+:17]([O-:19])=[O:18])([N+:14]([O-:16])=[O:15])[F:13])(Cl)Cl>ClCCCl>[F:13][C:12]([N+:17]([O-:19])=[O:18])([N+:14]([O-:16])=[O:15])[CH2:11][O:10][C:9]([Cl:1])([O:30][CH2:31][C:32]([F:39])([N+:36]([O-:38])=[O:37])[N+:33]([O-:35])=[O:34])[O:20][CH2:21][C:22]([F:23])([N+:27]([O-:29])=[O:28])[N+:24]([O-:26])=[O:25]

Participants

4

Reactant 2

HCID 24526ChlorineHCID 131492082-{Bis(2-fluoro-2,2-dinitroethoxy)[(trichloromethyl)disulfanyl]methoxy}-1-fluoro-1,1-dinitroethane

Product 1

HCID 14047294HCID 14047294, compound

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

Dry chlorine gas was passed for 2 hrs into a solution of 81.0 g (0.124 mole) of tris(2-fluoro-2,2-dinitroethoxy)methyl trichloromethyl disulfide in 300 ml of dry 1,2-dichloroethane at 60°-65° C. The solution was allowed to stand at ambient temperature overnight before the volatiles were removed with a stream of nitrogen and heating at 60°-65° C. The cooled residue was stirred with 300 ml of dry hexanes to give tris(2-fluoro-2,2-dinitroethyl)chloroorthoformate as an insoluble white solid. The hexanes solution was decanted from the solid which was washed with hexanes.

Workup

  1. customwere removed with a stream of nitrogen
  2. temperatureheating at 60°-65° C

Sources & evidence

ORD record
ord-707997d38c7a4b7c9acebb6a766810e4
Source dataset
uspto-grants-1989_07
Patent number
US04849540

Reaction notes

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