Tetrahydrofuran → N-(5'-Bromo-4-(trifluoromethyl)spiro[cyclohexane-1,2'-indene]-3'(1'H)-ylidene)-2-methylpropane-2-sulfinamide

HRID 2320036Notes

Reaction equation

HRID 2320036 reaction equation
[Br:8][c:9]1[cH:10][cH:11][c:12]2[c:25]([cH:26]1)[C:24](=[O:27])[C:14]1([CH2:13]2)[CH2:15][CH2:16][CH:17]([C:20]([F:21])([F:22])[F:23])[CH2:18][CH2:19]1.[CH2:28]1[O:29][CH2:30][CH2:31][CH2:32]1.[CH3:1][C:2]([CH3:3])([CH3:4])[S:5](=[O:6])[NH2:7].[CH3:33][CH2:34][O-:35].[CH3:37][CH2:38][O-:39].[CH3:40][CH2:41][O-:42].[CH3:43][CH2:44][O-:45].[Ti+4:36]>>[CH3:1][C:2]([CH3:3])([CH3:4])[S:5](=[O:6])[N:7]=[C:24]1[C:14]2([CH2:13][c:12]3[cH:11][cH:10][c:9]([Br:8])[cH:26][c:25]31)[CH2:15][CH2:16][CH:17]([C:20]([F:21])([F:22])[F:23])[CH2:18][CH2:19]2

Participants

6

Reactant 5

HCID 8028TetrahydrofuranHCID 114942Titanium cation (4+)HCID 1194401-Hydroxyethyl radical4×HCID 3382465Tert-ButanesulfinamideHCID 679795566'-Bromo-4-(trifluoromethyl)spiro[cyclohexane-1,2'-inden]-1'(3'H)-one

Product 1

HCID 67979375N-(5'-Bromo-4-(trifluoromethyl)spiro[cyclohexane-1,2'-indene]-3'(1'H)-ylidene)-2-methylpropane-2-sulfinamide

Sources & evidence

ORD record
ord-93b41bc588014a7bbe0510090591344f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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