Methanol → HCID 173183387, compound

HRID 2320047Notes

Reaction equation

HRID 2320047 reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[CH:5]1[CH:6]([O:23][SiH:24]([c:25]2[cH:26][cH:27][cH:28][cH:29][cH:30]2)[c:31]2[cH:32][cH:33][cH:34][cH:35][cH:36]2)[N:7]([c:9]2[s:10][cH:11][c:12]([C:14]([N:15]([CH3:16])[CH2:17][CH2:18][N:19]=[N+:20]=[N-:21])=[O:22])[n:13]2)[CH2:8]1.[CH2:60]([Cl:61])[Cl:62].[CH3:51][CH2:52][N:53]([CH2:54][CH3:55])[CH2:56][CH3:57].[CH3:58][OH:59].[N+:37](=[O:38])([O-:39])[c:40]1[cH:41][cH:42][c:43]([CH2:44][O:45][C:46](=[O:47])[Cl:48])[cH:49][cH:50]1.[OH-:63].[OH-:65].[Pd+2:64]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[CH:5]1[CH:6]([O:23][SiH:24]([c:25]2[cH:26][cH:27][cH:28][cH:29][cH:30]2)[c:31]2[cH:32][cH:33][cH:34][cH:35][cH:36]2)[N:7]([c:9]2[s:10][cH:11][c:12]([C:14]([N:15]([CH3:16])[CH2:17][CH2:18][NH:19][C:46]([O:45][CH2:44][c:43]3[cH:42][cH:41][c:40]([N+:37](=[O:38])[O-:39])[cH:50][cH:49]3)=[O:47])=[O:22])[n:13]2)[CH2:8]1

Participants

8

Reactant 7

HCID 887MethanolHCID 961Hydroxide2×HCID 6344DichloromethaneHCID 8471TriethylamineHCID 782054-Nitrobenzyl chloroformateHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 178484391HCID 178484391, compound

Product 1

HCID 173183387HCID 173183387, compound

Sources & evidence

ORD record
ord-7e20ce1ea6ad45cdaf4b2c0ba6e77486
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

Loading…