HRID2321411

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID8028

Tetrahydrofuran

C4H8O

HCID12679

Hexamethylphosphoramide

C6H18N3OP

结构：CCCCCCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1

HCID3084856

Octyl(triphenyl)phosphonium

C26H32P+

结构：COC1C(C)COC(C=O)C1O[Si](C)(C)C(C)(C)C

HCID19699692

未命名化合物

HCID178418339

Butyllithium

C4H9Li

PRODUCTS

生成物

结构：CCCCCCCC=CC1OCC(C)C(OC)C1O[Si](C)(C)C(C)(C)C

HCID178442761

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7900477801f54e0fa67f2ddd6699d472
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (10/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (10/10)

反应 SMILES

[Br-:1].[CH2:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])[P+:10]([c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1)([c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1)[c:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1.[CH2:53]1[O:54][CH2:55][CH2:56][CH2:57]1.[CH3:29][CH2:30][CH2:31][CH2:32][Li:33].[CH3:34][O:35][CH:36]1[CH:37]([O:45][Si:46]([CH3:47])([CH3:48])[C:49]([CH3:50])([CH3:51])[CH3:52])[CH:38]([CH:43]=[O:44])[O:39][CH2:40][CH:41]1[CH3:42].[CH3:58][N:59]([CH3:60])[P:61]([N:62]([CH3:63])[CH3:64])([N:65]([CH3:66])[CH3:67])=[O:68]>>[CH:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])=[CH:43][CH:38]1[CH:37]([O:45][Si:46]([CH3:47])([CH3:48])[C:49]([CH3:50])([CH3:51])[CH3:52])[CH:36]([O:35][CH3:34])[CH:41]([CH3:42])[CH2:40][O:39]1