Bromide ion → HCID 178442761, compound

HRID 2321411Notes

Reaction equation

HRID 2321411 reaction equation
[Br-:1].[CH2:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])[P+:10]([c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1)([c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1)[c:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1.[CH2:53]1[O:54][CH2:55][CH2:56][CH2:57]1.[CH3:29][CH2:30][CH2:31][CH2:32][Li:33].[CH3:34][O:35][CH:36]1[CH:37]([O:45][Si:46]([CH3:47])([CH3:48])[C:49]([CH3:50])([CH3:51])[CH3:52])[CH:38]([CH:43]=[O:44])[O:39][CH2:40][CH:41]1[CH3:42].[CH3:58][N:59]([CH3:60])[P:61]([N:62]([CH3:63])[CH3:64])([N:65]([CH3:66])[CH3:67])=[O:68]>>[CH:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])=[CH:43][CH:38]1[CH:37]([O:45][Si:46]([CH3:47])([CH3:48])[C:49]([CH3:50])([CH3:51])[CH3:52])[CH:36]([O:35][CH3:34])[CH:41]([CH3:42])[CH2:40][O:39]1

Participants

7

Reactant 6

HCID 259Bromide ionHCID 8028TetrahydrofuranHCID 12679HexamethylphosphoramideHCID 3084856Octyl(triphenyl)phosphoniumHCID 196996923-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]tetrahydro-4-methoxy-5-methyl-2H-pyran-2-carboxaldehydeHCID 178418339Butyllithium

Product 1

HCID 178442761HCID 178442761, compound

Sources & evidence

ORD record
ord-7900477801f54e0fa67f2ddd6699d472
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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