Sodium Azide → HCID 178441487, compound

HRID 232922Notes

Reaction equation

HRID 232922 reaction equation
[CH2:1]([C:5]1[N:9]([CH2:10][C:11]2[CH:16]=[CH:15][C:14]([C:17]3[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=3[C:23]#[N:24])=[CH:13][CH:12]=2)[C:8]2[CH:25]=[C:26]([N:30]3[CH2:35][CH2:34][CH2:33][CH2:32][C:31]3=[O:36])[CH:27]=[C:28]([CH3:29])[C:7]=2[N:6]=1)[CH2:2][CH2:3][CH3:4].[N-:37]=[N+:38]=[N-:39].[Na+]>CN(C)C=O>[CH2:1]([C:5]1[N:9]([CH2:10][C:11]2[CH:12]=[CH:13][C:14]([C:17]3[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=3[C:23]3[NH:39][N:38]=[N:37][N:24]=3)=[CH:15][CH:16]=2)[C:8]2[CH:25]=[C:26]([N:30]3[CH2:35][CH2:34][CH2:33][CH2:32][C:31]3=[O:36])[CH:27]=[C:28]([CH3:29])[C:7]=2[N:6]=1)[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 54294864HCID 54294864, compound

Product 1

HCID 178441487HCID 178441487, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Prepared analogously to Example 10 from 4'-[[2-n-butyl-4-methyl-6-(2-oxo-piperidin-1-yl)-benzimidazol-1-yl]-methyl]-2-cyano-biphenyl and sodium azide in dimethyl-formamide.

Sources & evidence

ORD record
ord-d75d5ef60c054947b3ed1bdf50f8092b
Source dataset
uspto-grants-1997_01
Patent number
US05591762

Reaction notes

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