5-Fluoro-1-pentofuranosylpyrimidine-2,4(1H,3H)-dione → 1-(3,4-Dihydroxy-5-methyl-2-oxolanyl)-5-fluoropyrimidine-2,4-dione

HRID 2329315Notes

Reaction equation

HRID 2329315 reaction equation
[F:19][C:20]([F:21])([F:22])[C:23]([OH:24])=[O:25].[F:1][c:2]1[c:3](=[O:18])[nH:4][c:5](=[O:17])[n:6]([CH:7]2[CH:8]([OH:9])[CH:10]([OH:11])[CH:12]([CH2:13][OH:14])[O:15]2)[cH:16]1>>[F:1][c:2]1[c:3](=[O:18])[nH:4][c:5](=[O:17])[n:6]([CH:7]2[CH:8]([OH:9])[CH:10]([OH:11])[CH:12]([CH3:13])[O:15]2)[cH:16]1

Participants

3

Reactant 2

HCID 18215-Fluoro-1-pentofuranosylpyrimidine-2,4(1H,3H)-dioneHCID 6422Trifluoroacetic acid

Product 1

HCID 31591-(3,4-Dihydroxy-5-methyl-2-oxolanyl)-5-fluoropyrimidine-2,4-dione

Sources & evidence

ORD record
ord-b0c52bab90fc40a982cb1145929d8084
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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