Sodium Azide → HCID 178439894, compound

HRID 232942Notes

Reaction equation

HRID 232942 reaction equation
[CH2:1]([C:4]1[N:8]([CH2:9][C:10]2[CH:15]=[CH:14][C:13]([C:16]3[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=3[C:22]#[N:23])=[CH:12][CH:11]=2)[C:7]2[CH:24]=[C:25]([C:30]3[N:34]([CH3:35])[C:33]4[CH:36]=[CH:37][CH:38]=[CH:39][C:32]=4[N:31]=3)[CH:26]=[C:27]([CH2:28][CH3:29])[C:6]=2[N:5]=1)[CH2:2][CH3:3].[N-:40]=[N+:41]=[N-:42].[Na+]>CN(C)C=O>[CH2:1]([C:4]1[N:8]([CH2:9][C:10]2[CH:11]=[CH:12][C:13]([C:16]3[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=3[C:22]3[NH:42][N:41]=[N:40][N:23]=3)=[CH:14][CH:15]=2)[C:7]2[CH:24]=[C:25]([C:30]3[N:34]([CH3:35])[C:33]4[CH:36]=[CH:37][CH:38]=[CH:39][C:32]=4[N:31]=3)[CH:26]=[C:27]([CH2:28][CH3:29])[C:6]=2[N:5]=1)[CH2:2][CH3:3]

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 54424412HCID 54424412, compound

Product 1

HCID 178439894HCID 178439894, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Prepared analogously to Example 10 from 4'-[(2-n-propyl-4-ethyl-6-(1-methylbenzimidazol-2-yl)-benzimidazol-1-yl)-methyl]-2-cyano-biphenyl and sodium azide in dimethylformamide.

Sources & evidence

ORD record
ord-537eb32f84904361ab01668c4c1bfa75
Source dataset
uspto-grants-1997_01
Patent number
US05591762

Reaction notes

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