Sodium Azide → HCID 178422997, compound

HRID 232946Notes

Reaction equation

HRID 232946 reaction equation
[CH:1]1([C:5]2[N:9]([CH2:10][C:11]3[CH:16]=[CH:15][C:14]([C:17]4[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=4[C:23]#[N:24])=[CH:13][CH:12]=3)[C:8]3[CH:25]=[C:26]([C:30]4[N:34]([CH3:35])[C:33]5[CH:36]=[CH:37][CH:38]=[CH:39][C:32]=5[N:31]=4)[CH:27]=[C:28]([CH3:29])[C:7]=3[N:6]=2)[CH2:4][CH2:3][CH2:2]1.[N-:40]=[N+:41]=[N-:42].[Na+]>CN(C)C=O>[CH:1]1([C:5]2[N:9]([CH2:10][C:11]3[CH:16]=[CH:15][C:14]([C:17]4[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=4[C:23]4[NH:42][N:41]=[N:40][N:24]=4)=[CH:13][CH:12]=3)[C:8]3[CH:25]=[C:26]([C:30]4[N:34]([CH3:35])[C:33]5[CH:36]=[CH:37][CH:38]=[CH:39][C:32]=5[N:31]=4)[CH:27]=[C:28]([CH3:29])[C:7]=3[N:6]=2)[CH2:4][CH2:3][CH2:2]1

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 19964922HCID 19964922, compound

Product 1

HCID 178422997HCID 178422997, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Prepared analogously to Example 10 from 4'-[(2-cyclobutyl-4-methyl-6-(1-methylbenzimidazol-2-yl)-benzimidazol-1-yl)-methyl]-2-cyano-biphenyl and sodium azide in dimethylformamide.

Sources & evidence

ORD record
ord-ce4d7cc5eab84c28b871d8fe5513963e
Source dataset
uspto-grants-1997_01
Patent number
US05591762

Reaction notes

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