Dimethyl Sulfoxide → 2-Bromo-9,9-didecyl-7-iodo-9H-fluorene

HRID 2332100Notes

Reaction equation

HRID 2332100 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:13]([cH:14]1)[C:12]([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[c:11]1[c:6]-2[cH:7][cH:8][c:9]([CH:35]=[O:36])[cH:10]1.[Br:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH3:51].[CH3:52][S:53]([CH3:54])=[O:55].[I-:38].[K+:37].[K+:40].[OH-:39]>>[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:13]([cH:14]1)[C:12]([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[c:11]1[c:6]-2[cH:7][cH:8][c:9]([I:38])[cH:10]1

Participants

7

Reactant 6

HCID 679Dimethyl SulfoxideHCID 813Potassium Cation2×HCID 961HydroxideHCID 81731-BromodecaneHCID 30165Iodide IonHCID 22723474HCID 22723474, compound

Product 1

HCID 227234762-Bromo-9,9-didecyl-7-iodo-9H-fluorene

Sources & evidence

ORD record
ord-69a1c3672f32406bae498a2da2ad1a8e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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