Potassium Cation → Tert-butyl 6-bromo-2H-chromene-3-carboxylate

HRID 2333752Notes

Reaction equation

HRID 2333752 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([OH:10])[c:6]([CH:7]=[O:8])[cH:9]1.[C:11]([CH:12]=[CH2:13])(=[O:14])[O:15][C:16]([CH3:17])([CH3:18])[CH3:19].[C:32]([OH:33])([CH3:34])([CH3:35])[CH3:36].[CH3:20][C:21]([CH3:22])([O-:23])[CH3:24].[CH3:26][CH2:27][O:28][C:29](=[O:30])[CH3:31].[K+:25]>>[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:6]([cH:9]1)[CH:7]=[C:12]([C:11](=[O:14])[O:15][C:16]([CH3:17])([CH3:18])[CH3:19])[CH2:13][O:10]2

Participants

7

Reactant 6

HCID 813Potassium CationHCID 6386tert-ButanolHCID 8857Ethyl AcetateHCID 15458tert-Butyl acrylateHCID 728635-BromosalicylaldehydeHCID 45749132-Methylpropan-2-olate

Product 1

HCID 10566979Tert-butyl 6-bromo-2H-chromene-3-carboxylate

Sources & evidence

ORD record
ord-c199073c84c64eefb5888b3fc0dc58b5
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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