Trimethyl phosphite → Dimethyl [(3-methylphenyl)methyl]phosphonate

HRID 233442Notes

Reaction equation

F[C:2]1[CH:14]=[CH:13][C:5]([CH2:6][P:7](=[O:12])([O:10][CH3:11])[O:8][CH3:9])=[CH:4][CH:3]=1.[CH3:15]C1C=C(C=CC=1)CBr.COP(OC)OC>>[CH3:15][C:3]1[CH:4]=[C:5]([CH:13]=[CH:14][CH:2]=1)[CH2:6][P:7](=[O:12])([O:10][CH3:11])[O:8][CH3:9]

Participants

Reactant 3

HCID 8472Trimethyl phosphite

HCID 12099m-Xylyl bromide

HCID 23208053HCID 23208053, compound

Product 1

HCID 2773781Dimethyl [(3-methylphenyl)methyl]phosphonate

Procedure

Following the procedure of Compound 11, 3-methylbenzyl bromide is reacted with trimethylphosphite.

Sources & evidence

ORD record: ord-d483430e27d04ed1bafcaeba34d043fc
Source dataset: uspto-grants-1997_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05593980

Reaction notes

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