HRID2334668

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID923

Sodium ion

Na+

HCID6228

N,N-Dimethylformamide

C3H7NO

HCID30165

Iodide ion

I-

HCID74499

Trimethylsulfoxonium

C3H9OS+

HCID166653

Hydride

H-

结构：C[Si](C)(C)CCOCn1nc(I)c2ccc(C=C3C(=O)Nc4ccc(F)cc43)cc21

HCID66734439

未命名化合物

PRODUCTS

生成物

结构：C[Si](C)(C)CCOCn1nc(I)c2ccc(C3CC34C(=O)Nc3ccc(F)cc34)cc21

HCID67954635

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-113dbcbb7f9c4dd18949a8c5c6275ac5
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (10/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (10/10)

反应 SMILES

[CH3:2][S+:3]([CH3:4])([CH3:5])=[O:6].[F:9][c:10]1[cH:11][c:12]2[c:16]([cH:17][cH:18]1)[NH:15][C:14](=[O:19])[C:13]2=[CH:20][c:21]1[cH:22][cH:23][c:24]2[c:25]([I:38])[n:26][n:27]([CH2:30][O:31][CH2:32][CH2:33][Si:34]([CH3:35])([CH3:36])[CH3:37])[c:28]2[cH:29]1.[H-:7].[I-:1].[Na+:8].[O:39]=[CH:40][N:41]([CH3:42])[CH3:43]>>[CH2:2]1[C:13]2([c:12]3[cH:11][c:10]([F:9])[cH:18][cH:17][c:16]3[NH:15][C:14]2=[O:19])[CH:20]1[c:21]1[cH:22][cH:23][c:24]2[c:25]([I:38])[n:26][n:27]([CH2:30][O:31][CH2:32][CH2:33][Si:34]([CH3:35])([CH3:36])[CH3:37])[c:28]2[cH:29]1