Ammonia → [3-(Tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-3-enyl]-acetaldehyde

HRID 2336552Notes

Reaction equation

HRID 2336552 reaction equation
[C:49]([CH3:50])([CH3:51])([CH3:52])[SiH2:53][O:54][C:55]([C:56]1=[CH:61][CH2:60][CH2:59][CH:58]([CH2:62][CH2:63][OH:64])[CH2:57]1)([CH3:65])[CH3:66].[CH2:1]([O:2][CH2:3][CH2:4][CH:5]1[CH2:6][C:7]([CH2:8][O:9][Si:10]([C:11]([CH3:12])([CH3:13])[CH3:14])([CH3:15])[CH3:16])=[CH:17][CH2:18][CH2:19]1)[c:20]1[cH:21][cH:22][cH:23][cH:24][cH:25]1.[CH2:31]([O:32][CH2:33][CH2:34][CH:35]1[CH2:36][C:37]([CH2:38][OH:39])=[CH:40][CH2:41][CH2:42]1)[c:43]1[cH:44][cH:45][cH:46][cH:47][cH:48]1.[CH2:67]1[O:68][CH2:69][CH2:70][CH2:71]1.[CH3:27][S:28]([CH3:29])=[O:30].[Cl:72][CH2:73][Cl:74].[NH3:26]>>[C:49]([CH3:50])([CH3:51])([CH3:52])[SiH2:53][O:54][C:55]([C:56]1=[CH:61][CH2:60][CH2:59][CH:58]([CH2:62][CH:63]=[O:64])[CH2:57]1)([CH3:65])[CH3:66]

Participants

8

Reactant 7

HCID 222AmmoniaHCID 679Dimethyl SulfoxideHCID 6344DichloromethaneHCID 8028TetrahydrofuranHCID 21879598[5-(2-Benzyloxy-ethyl)-cyclohex-1-enylmethoxy]-tert-butyl-dimethyl-silaneHCID 21879600{5-[2-(Benzyloxy)ethyl]cyclohex-1-en-1-yl}methanolHCID 1317269402-[3-(Tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-3-enyl]-ethanol

Product 1

HCID 131726104[3-(Tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-3-enyl]-acetaldehyde

Sources & evidence

ORD record
ord-64395640f2e74242a70c2b365fd1c22d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

Loading…