Bromide ion → Spiro[2.5]octan-5-one

HRID 2339818Notes

Reaction equation

HRID 2339818 reaction equation
[Br-:10].[CH2:11]([CH3:12])[Mg+:13].[CH3:1][O:2][C:3]1=[CH:4][C:5](=[O:9])[CH2:6][CH2:7][CH2:8]1.[CH3:26][CH2:27][O:28][CH2:29][CH3:30].[CH3:31][CH:32]([CH3:33])[O-:34].[CH3:35][CH:36]([CH3:37])[O-:38].[CH3:39][CH:40]([CH3:41])[O-:42].[CH3:43][CH:44]([CH3:45])[O-:46].[OH2:14].[Ti+4:47].[c:15]1([CH3:16])[cH:17][cH:18][c:19]([S:20]([OH:21])(=[O:22])=[O:23])[cH:24][cH:25]1>>[C:3]12([CH2:4][C:5](=[O:9])[CH2:6][CH2:7][CH2:8]1)[CH2:11][CH2:12]2

Participants

9

Reactant 8

HCID 259Bromide ionHCID 962WaterHCID 3283Diethyl EtherHCID 6101p-Toluenesulfonic acidHCID 855973-Methoxycyclohex-2-en-1-oneHCID 114942Titanium cation (4+)HCID 3260420Isopropanolate4×HCID 178461628HCID 178461628, compound

Product 1

HCID 12153480Spiro[2.5]octan-5-one

Sources & evidence

ORD record
ord-64daed74c67441c1a302435ad1e9e9ec
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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