HCID 53663285, compound → 88467-55-4

HRID 2350834Notes

Reaction equation

HRID 2350834 reaction equation
[Br:1][CH2:2][CH2:3][CH:4]=[C:5]([CH3:9])[CH2:6][CH2:7][CH3:8]>C(O)(=O)C.[Pt]=O>[Br:1][CH2:2][CH2:3][CH2:4][CH:5]([CH3:9])[CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 1

HCID 53663285HCID 53663285, compound

Product 1

HCID 1358849388467-55-4Yield 70%

Reagents, catalysts & solvents 2

HCID 82844Platinum oxide (PtO)CatalystHCID 176Acetic AcidSolvent

Procedure

This was prepared from compound (1) in 70% yield by hydrogenation over platinum oxide in glacial acetic acid: b.p. 67°-70° C. at 8.5 mm; NMR (CDCl3) 0.86 (t, CH3CH2), 0.87 (d, CH3CH), 3.40 (m, 2H, CH2CH2Br)). The IR and NMR spectra of the compound were in complete agreement with the assigned structure and reported values.

Sources & evidence

ORD record
ord-507a8b6f74524016a9c0d5e586da26b5
Source dataset
uspto-grants-1989_10
Patent number
US04871537

Reaction notes

Loading…