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HRID2351794

反应详情

EQUATION

反应方程式

HRID 2351794 的结构方程式

REACTANTS

反应物

2
结构：CCC[CH2][SnH]([CH2]CCC)[CH2]CCC
HCID5948

Tributyltin

C12H28Sn

结构：C#CC(CCCCC)O[Si](C)(C)C(C)(C)C
HCID11791325

tert-Butyl(dimethyl)[(1-pentylprop-2-ynyl)oxy]silane

C14H28OSi

PRODUCTS

生成物

1
结构：CCCCCC(/C=[CH]/[Sn]([CH2]CCC)([CH2]CCC)[CH2]CCC)O[Si](C)(C)C(C)(C)C
HCID10414672

未命名化合物

PROCEDURE

实验过程

Irradiation of 3-(tert-butyldimethylsilyloxy)-1-octyne (48, 2.05 g, 8.53 mmol) and tributyltin hydride (2.30 mL, 8.53 mmol) under the conditions described above yielded 50: 1H NMR (CDCl3) δ 6.04 (d, J=19.0 Hz, 1H), 5.93 (dd, J1 =19.0 Hz, J2 =5.2 Hz, 1H), 4.04 (dd, J1 =6.1 Hz, J2 =5.6 Hz, 1H), 1.52, 1.34 (2m, 26H), 0.94 (m, 21H), 0.07 (s, 3H), 0.05 (s, 3H). 1H NMR analysis revealed that 50 was only 85% pure and presumably contained the same isomeric impurities as did 49.