Tert-Butyl hypochlorite → HCID 54172172, compound

HRID 2352674Notes

Reaction equation

HRID 2352674 reaction equation
[Cl:1]OC(C)(C)C.[CH2:7]([S:13][CH2:14][CH:15]=[CH2:16])[CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]>C(Cl)Cl>[CH2:7]([S:13][CH:14]=[CH:15][CH2:16][Cl:1])[CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 521297Tert-Butyl hypochloriteHCID 7010427ALLYL N-HEXYL SULFIDE

Product 1

HCID 54172172HCID 54172172, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Tert-butyl hypochlorite (2.06 g, 19.0 mmol) is added dropwise at -50° to a solution of 3-hexylthio-1-propene (3.0 g, 19.0 mmol) in 20 ml of methylene chloride. The mixture is allowed to warm to RT and is then stripped of solvent to give 3-hexylthio-2-propenyl chloride.

Sources & evidence

ORD record
ord-a170d962d9b34614b4c37c38f98e250a
Source dataset
uspto-grants-1989_10
Patent number
US04877899

Reaction notes

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