Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Iodohexadecane → 1-Hexadecyl-2-methoxybenzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Iodohexadecane | HCID 11007 | — |
| 반응물 | 2-Bromoanisole | HCID 11358 | — |
| 반응물 | Magnesium | HCID 5462224 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 1-Hexadecyl-2-methoxybenzene | HCID 20218652 | 102% |
반응 단계
To a refluxing solution of about 35.3 g of hexadecyl iodide in tetrahydrofuran was added a solution of about 37.4 g of bromoanisole and about 4.86 g of magnesium in tetrahydrofuran which had been refluxed for about 2 hours. An about 10 ml portion of about 0.1M lithium cupric chloride was added, the mixture was refluxed about 2 hours and stirred at room temperature for about 16 hours giving about 34 g of the desired reagent.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04640913 |
| 출처 데이터셋 | uspto-grants-1987_02 |
| ORD ID | ord-79e0827f7dc4487992b562bca3ef6639 |
| 출처 메모 | uspto-grants-1987_02 |