Hydrochloric Acid → HCID 57448039, compound

HRID 2358109Notes

Reaction equation

HRID 2358109 reaction equation
[CH3:1][C:2]1[C:7]([S:8]([CH3:11])(=[O:10])=[O:9])=[CH:6][CH:5]=[CH:4][C:3]=1[C:12]1[CH:17]=[CH:16][N:15]=[CH:14][CH:13]=1.Cl>[Pt]=O.CO>[CH3:1][C:2]1[C:7]([S:8]([CH3:11])(=[O:10])=[O:9])=[CH:6][CH:5]=[CH:4][C:3]=1[CH:12]1[CH2:17][CH2:16][NH:15][CH2:14][CH2:13]1

Participants

5

Reactant 2

HCID 313Hydrochloric AcidHCID 57448063Pyridine, 4-[2-methyl-3-(methylsulfonyl)phenyl]-

Product 1

HCID 57448039HCID 57448039, compound

Reagents, catalysts & solvents 2

HCID 82844Platinum oxide (PtO)CatalystHCID 887MethanolSolvent

Procedure

Preparation according to preparation 9: 4-[2-methyl-3-(methylsulfonyl)phenyl]pyridine (0.4 g, 1.6 mmol), methanol (10 ml), platinum oxide (0.10 g), hydrochloric acid (0.1 ml, conc). Yield: 0.41 g. MS m/z (rel. intensity, 70 eV) 247 (M+, 96), 246 (51), 168 (53), 167 (bp), 139 (51).

Workup

  1. customPreparation
  2. customaccording to preparation 9

Sources & evidence

ORD record
ord-f717a2ec66094652b17c534a5c1803cd
Source dataset
uspto-grants-2010_07
Patent number
US07763639B2

Reaction notes

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