HRID2361536

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：Cc1ccc(S(=O)(=O)[O-])cc1.Oc1ccc([S+](c2ccccc2)c2ccccc2)cc1

HCID22389781

未命名化合物

结构：C=C(C)C(=O)OC(C(F)(F)F)C(F)(F)S(=O)(=O)[O-].CC[NH+](CC)CC

HCID86656197

未命名化合物

PRODUCTS

生成物

结构：C=C(C)C(=O)OC(C(F)(F)F)C(F)(F)S(=O)(=O)[O-].Oc1ccc([S+](c2ccccc2)c2ccccc2)cc1

HCID86656198

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID21908982

未命名化合物

PROCEDURE

实验过程

4-hydroxyphenyldiphenylsulfonium 4-methylbenzenesulfonate and triethylammonium 1,1,3,3,3-pentafluoro-2-(methacryloyloxy)propane-1-sulfonate of Synthesis Example 1-2 are mixed and ion-changed in a dichloromethane-water system. An organic layer after washing by water was concentrated under reduced pressure and was used for the next reaction as a crude substance.

WORKUP

后处理

additionare mixed
washAn organic layer after washing by water
concentrationwas concentrated under reduced pressure
customwas used for the next reaction as a crude substance

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-60df5302d4704d9a9c671255a6400603
来源数据集: uspto-grants-2014_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08691490B2
来源说明: uspto-grants-2014_04

反应 SMILES

CC1C=CC(S([O-])(=O)=O)=CC=1.[OH:12][C:13]1[CH:18]=[CH:17][C:16]([S+:19]([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)=[CH:15][CH:14]=1.[F:32][C:33]([F:49])([S:45]([O-:48])(=[O:47])=[O:46])[CH:34]([O:39][C:40](=[O:44])[C:41]([CH3:43])=[CH2:42])[C:35]([F:38])([F:37])[F:36].C([NH+](CC)CC)C>ClCCl.O>[F:49][C:33]([F:32])([S:45]([O-:48])(=[O:46])=[O:47])[CH:34]([O:39][C:40](=[O:44])[C:41]([CH3:43])=[CH2:42])[C:35]([F:36])([F:38])[F:37].[OH:12][C:13]1[CH:18]=[CH:17][C:16]([S+:19]([C:26]2[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=2)[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)=[CH:15][CH:14]=1