Hydroxylamine, O-ethyl- → HCID 53822451, compound

HRID 236247Notes

Reaction equation

HRID 236247 reaction equation
[CH3:1][C:2]1[CH:3]=[C:4]2[C:8](=[C:9]([CH3:11])[CH:10]=1)[C:7]1([CH2:16][C:15](=[O:17])[CH:14]([C:18](=O)[CH2:19][CH3:20])[C:13](=[O:22])[CH2:12]1)[CH2:6][CH2:5]2.[CH2:23]([O:25][NH2:26])[CH3:24]>>[CH3:1][C:2]1[CH:3]=[C:4]2[C:8](=[C:9]([CH3:11])[CH:10]=1)[C:7]1([CH2:16][C:15](=[O:17])[CH:14]([C:18](=[N:26][O:25][CH2:23][CH3:24])[CH2:19][CH3:20])[C:13](=[O:22])[CH2:12]1)[CH2:6][CH2:5]2

Participants

3

Reactant 2

HCID 69357Hydroxylamine, O-ethyl-HCID 14348619HCID 14348619, compound

Product 1

HCID 53822451HCID 53822451, compound

Procedure

Reaction of 5',7'-dimethyl-4-propionylspiro[cyclohexane-1,1'-indan]-3,5-dione with ethoxyamine according to the procedure described in Example 1 part (c) gave 5',7'-dimethyl-4-[1-(ethoxyimino)propyl]spiro[cyclohexane-1,1'indan]-3,5-dione (1) as a pale yellow oil which was characterized by its proton magnetic resonance spectrum and the spectroscopic data is recorded in Table 2, Example 12.

Sources & evidence

ORD record
ord-6ba9fc994ef64f1b8894618c0f590c12
Source dataset
uspto-grants-1987_02
Patent number
US04643763

Reaction notes

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