Dichloromethane → Chloromethyl 2-cyanoethylether

HRID 2363676Notes

Reaction equation

HRID 2363676 reaction equation
CS[CH2:3][CH:4]([C:14]#[N:15])[CH2:5][O:6][CH2:7][CH:8]([C:12]#[N:13])CSC.S(Cl)([Cl:19])(=O)=O.[CH2:21]([Cl:23])Cl>>[Cl:19][CH2:3][CH:4]([C:14]#[N:15])[CH2:5][O:6][CH2:7][CH:8]([C:12]#[N:13])[CH2:21][Cl:23]

Participants

4

Reactant 3

HCID 6344DichloromethaneHCID 24648Sulfuryl chlorideHCID 86616732Methylthiomethyl 2-cyanoethylether

Product 1

HCID 86616731Chloromethyl 2-cyanoethylether

Procedure

Methylthiomethyl 2-cyanoethylether (3.3 g, 25 mmol) was dissolved in 70 mL of methylene chloride, and 2 mL of sulfuryl chloride (25 mmol) was added dropwise, and the reaction was further performed at room temperature for 1 hour.

Sources & evidence

ORD record
ord-9eef10283fa44218be2307d7308f4d43
Source dataset
uspto-grants-2014_04
Patent number
US08691970B2

Reaction notes

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