m-Chloroperbenzoic acid → HCID 13893138, compound

HRID 236564Notes

Reaction equation

HRID 236564 reaction equation
[C:1]([O:5][C:6]([NH:8][CH:9]([CH2:20][CH:21]([CH3:23])[CH3:22])[CH:10]([OH:19])[CH2:11][S:12][CH:13]1[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]1)=[O:7])([CH3:4])([CH3:3])[CH3:2].ClC1C=C(C=CC=1)C(OO)=[O:29]>ClCCl>[C:1]([O:5][C:6]([NH:8][CH:9]([CH2:20][CH:21]([CH3:23])[CH3:22])[CH:10]([OH:19])[CH2:11][S:12]([CH:13]1[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]1)=[O:29])=[O:7])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 13893088HCID 13893088, compound

Product 1

HCID 13893138HCID 13893138, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Treating the resultant compound of Example 3 with 1.05 equivalents of 3-chloroperoxybenzoic acid in dichloromethane, gave the desired compound after chromatography. Mass spectrum: M+ =361.

Sources & evidence

ORD record
ord-8b1f3466dc2e456ab297a5c0ba9be5b2
Source dataset
uspto-grants-1987_02
Patent number
US04645759

Reaction notes

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