3,4,5,6-Tetrahydrophthalic anhydride → HCID 21315655, compound

HRID 236679Notes

Reaction equation

HRID 236679 reaction equation
[C:1]1(=[O:11])[O:6][C:4](=O)[C:3]2[CH2:7][CH2:8][CH2:9][CH2:10][C:2]1=2.[F:12][C:13]([F:23])([F:22])[S:14][C:15]1[CH:21]=[CH:20][C:18]([NH2:19])=[CH:17][CH:16]=1>>[F:22][C:13]([F:12])([F:23])[S:14][C:15]1[CH:16]=[CH:17][C:18]([N:19]2[C:1](=[O:11])[C:2]3[CH2:10][CH2:9][CH2:8][CH2:7][C:3]=3[C:4]2=[O:6])=[CH:20][CH:21]=1

Participants

3

Reactant 2

HCID 124753,4,5,6-Tetrahydrophthalic anhydrideHCID 1230544-((Trifluoromethyl)thio)aniline

Product 1

HCID 21315655HCID 21315655, compoundYield 70.3%

Procedure

In a manner similar to above, 1.6 g (0.01 mole) of 3,4,5,6-tetrahydrophthalic anhydride and 2.0 g (0.01 mole) of p-trifluoromethylthioaniline were treated to obtain 2.3 g of N-(p-trifluoromethylthiophenyl)-3,4,5,6-tetrahydrophthalimide (melting point, 112°-114° C.; 70% yield).

Sources & evidence

ORD record
ord-23b9708487c64aa2a9a461419f18ed5f
Source dataset
uspto-grants-1979_06
Patent number
US04157256

Reaction notes

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