HRID236709

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID66289

Dimethyl cyanocarbonodithioimidate

C4H6N2S2

HCID239041

2-Propyn-1-amine

C3H5N

PRODUCTS

生成物

HCID2805748

Carbamimidothioic acid, N-cyano-N'-2-propynyl-, methyl ester

C6H7N3S

收率 81.3%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6342

Acetonitrile

C2H3N

PROCEDURE

实验过程

A solution of dimethyl cyanodithioimidocarbonate (16.00 g, 0.109 mole) and propargyl amine (6.03 g, 0.109 mole) in acetonitrile (320 ml) was stirred at reflux for 4 hours, and then at 25° for 12 hours. Workup gave the title compound A (13.58 g, 81%), mp 160°-164°.

WORKUP

后处理

temperatureat reflux for 4 hours