Sodium Bicarbonate → HCID 23717003, compound

HRID 236966Notes

Reaction equation

HRID 236966 reaction equation
[OH:1][C:2]1[C:15]2[C:14](=[O:16])[CH:13]=[C:12]([C:17]([O:19]CC)=[O:18])[O:11][C:10]=2[C:9]([CH2:22][CH2:23][CH3:24])=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[CH:7]2.C(=O)(O)[O-].[Na+:29]>O.C(O)C>[OH:1][C:2]1[C:15]2[C:14](=[O:16])[CH:13]=[C:12]([C:17]([O-:19])=[O:18])[O:11][C:10]=2[C:9]([CH2:22][CH2:23][CH3:24])=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[CH:7]2.[Na+:29]

Participants

5

Reactant 2

HCID 516892Sodium BicarbonateHCID 21314616HCID 21314616, compound

Product 1

HCID 23717003HCID 23717003, compound

Reagents, catalysts & solvents 2

HCID 702EthanolSolventHCID 962WaterSolvent

Procedure

The product of step (a) (6 g) was heated at 100° with sodium bicarbonate (1.55 g) in a mixture of water (50 ml) and ethanol (5 ml), for 4 hours. The ethanol was removed, in vacuo, and the remaining aqueous solution was filtered and cooled. The sodium salt (1.8 g) crystallised from this solution as orange needles.

Workup

  1. customThe ethanol was removed, in vacuo
  2. filtrationthe remaining aqueous solution was filtered
  3. temperaturecooled
  4. customThe sodium salt (1.8 g) crystallised from this solution as orange needles

Sources & evidence

ORD record
ord-ca0b2cf883084bc7b8bbd4b0d8eba3ad
Source dataset
uspto-grants-1979_06
Patent number
US04159273

Reaction notes

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