HuagongsheHuagongshe Chemistry Print Report · For research reference only
5-(p-Fluorophenyl)-3-hydrazino-1,2,4-triazine → 7-(p-Fluorophenyl)-3-methyl-1,2,4-triazolo[4,3-b]-1,2,4-triazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5-(p-Fluorophenyl)-3-hydrazino-1,2,4-triazine | HCID 12748649 | — |
| Reactant | Ethyl ortho-acetate | HCID 86598186 | — |
| Product | 7-(p-Fluorophenyl)-3-methyl-1,2,4-triazolo[4,3-b]-1,2,4-triazine | HCID 21315225 | — |
Reaction Steps
A mixture of 0.57 g. of 5-(p-fluorophenyl)-3-hydrazino-1,2,4-triazine and 20 ml. of ethyl orthoacetate is refluxed for 4 hours, cooled and filtered. The desired product is recovered as a brown solid, m.p. 227.5°-231° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04159375 |
| Source dataset | uspto-grants-1979_06 |
| ORD ID | ord-ef24a053df5940b8aa1d2965c95e8aba |
| Source note | uspto-grants-1979_06 |