Pyridine → HCID 67903428, compound

HRID 2371521Notes

Reaction equation

HRID 2371521 reaction equation
[Br:1][CH2:2][CH2:3][CH2:4][C:5]1[CH:10]=[CH:9][C:8]([CH2:11][CH2:12][CH2:13]Br)=[CH:7][CH:6]=1.[N:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.C(O[CH2:24][CH3:25])C>C(O)C>[Br-:1].[Br-:1].[N+:15]1([CH2:2][CH2:3][CH2:4][C:5]2[CH:10]=[CH:9][C:8]([CH2:11][CH2:12][CH2:13][N+:15]3[CH:25]=[CH:24][CH:18]=[CH:17][CH:16]=3)=[CH:7][CH:6]=2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1

Participants

5

Reactant 3

HCID 1049PyridineHCID 3283Diethyl EtherHCID 135926591,4-Bis(3-bromopropyl)benzene

Product 1

HCID 67903428HCID 67903428, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

First, 320 mg of 1,4-bis(3-bromopropyl)benzene was dissolved in 5.0 ml of ethanol, 202 μl of pyridine was added thereto, the mixture was then refluxed for 18 hours. After cooling, to the reaction mixture was added 20 ml of ethyl ether. The resulting solids were recrystallized from ethanol/ethyl ether to obtain 215 mg of the title compound as a colorless crystal.

Workup

  1. temperaturethe mixture was then refluxed for 18 hours
  2. temperatureAfter cooling, to the reaction mixture
  3. customThe resulting solids were recrystallized from ethanol/ethyl ether

Sources & evidence

ORD record
ord-eb62ebcf3d4341f5b9dbd17e6e38d83e
Source dataset
uspto-grants-1992_03
Patent number
US05093370

Reaction notes

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