Ethyl Acrylate → HCID 9976631, compound

HRID 2371709Notes

Reaction equation

HRID 2371709 reaction equation
[CH:1]1[C:11]2[CH:10]=[CH:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[C:6](=[C:16]3[CH2:21][CH2:20][NH:19][CH2:18][CH2:17]3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[C:22]([O:26][CH2:27][CH3:28])(=[O:25])[CH:23]=[CH2:24]>C(O)C>[CH:1]1[C:11]2[CH:10]=[CH:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[C:6](=[C:16]3[CH2:17][CH2:18][N:19]([CH2:24][CH2:23][C:22]([O:26][CH2:27][CH3:28])=[O:25])[CH2:20][CH2:21]3)[C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 8821Ethyl AcrylateHCID 1597184-(5H-Dibenzo(a,d)cyclohepten-5-ylidene)piperidine

Product 1

HCID 9976631HCID 9976631, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 4.00 g of 4-(5H-dibenzo[a,d]cyclohepten-5-ylidene)piperidine, 2.1 ml of ethyl acrylate and 20 ml of ethanol was refluxed for 1 hr and concentrated to give 5.35 g of colorless liquid. The liquid was purified by column chromatography on silica gel (eluent: chloroform) to give 5.3 g of colorless solid, which was recrystallized from n-hexane to give colorless crystals, mp 66°-67° C.

Workup

  1. temperaturewas refluxed for 1 hr
  2. concentrationconcentrated

Sources & evidence

ORD record
ord-6bc3bdc42cc04d899c4e5b40458e75cc
Source dataset
uspto-grants-1992_03
Patent number
US05095022

Reaction notes

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