2-Bromomethylnaphthalene → 3-Methoxy-4-(naphth-2-ylmethoxy)bromobenzene

HRID 2372499Notes

Reaction equation

HRID 2372499 reaction equation
Br[CH2:2][C:3]1[CH:12]=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=1.[Br:13][C:14]1[CH:19]=[CH:18][C:17]([OH:20])=[C:16]([O:21][CH3:22])[CH:15]=1>>[CH3:22][O:21][C:16]1[CH:15]=[C:14]([Br:13])[CH:19]=[CH:18][C:17]=1[O:20][CH2:2][C:3]1[CH:12]=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=1

Participants

3

Reactant 2

HCID 703202-BromomethylnaphthaleneHCID 2622344-Bromo-2-methoxyphenol

Product 1

HCID 200806073-Methoxy-4-(naphth-2-ylmethoxy)bromobenzeneYield 62%

Procedure

Using the procedure described in the first paragraph of Example 1 which is concerned with the preparation of starting materials, 2-bromomethylnaphthalene was reacted with 4-bromo -2-methoxyphenol to give 3-methoxy-4-(naphth-2-ylmethoxy)bromobenzene (62%), m.p. 108° C.

Sources & evidence

ORD record
ord-747ba90f450747d6b3d313cd95702b57
Source dataset
uspto-grants-1992_03
Patent number
US05098932

Reaction notes

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