Ethanol → HCID 19902347, compound

HRID 2372815Notes

Reaction equation

HRID 2372815 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([S:9][C:10]2[CH:17]=[CH:16][C:13]([C:14]#[N:15])=[CH:12][CH:11]=2)=[CH:5][CH:4]=1.[OH2:18].[OH2:19].O.O.O.O.C(O[O-])(=O)C1C(=CC=CC=1)C([O-])=O.[Mg+2].C(O)C>O>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]([S:9]([C:10]2[CH:17]=[CH:16][C:13]([C:14]#[N:15])=[CH:12][CH:11]=2)(=[O:19])=[O:18])=[CH:7][CH:8]=1

Participants

5

Reactant 3

HCID 702EthanolHCID 11172528Benzonitrile, 4-[(4-methoxyphenyl)thio]-HCID 21894687Magnesium 2-(dioxidan-2-ide-1-carbonyl)benzoate--water (1/1/6)

Product 1

HCID 19902347HCID 19902347, compoundYield 77%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

6 g (0.0248 mol) of 4-[(4-methoxyphenyl)thio]benzonitrile and then 18.45 g of magnesium monoperoxyphthalate hexahydrate are added to a mixture of 120 ml of ethanol and 12 ml of water. The reaction medium is kept at 40° C. for 20 minutes. After hydrolysis in iced water, the solution is filtered and the white solid is washed with water. 5.2 g (yield: 77%) of the expected product are thus obtained.

Workup

  1. filtrationthe solution is filtered
  2. washthe white solid is washed with water

Sources & evidence

ORD record
ord-677cfcaec45047f78c39ad71a87fc053
Source dataset
uspto-grants-1992_03
Patent number
US05100913

Reaction notes

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