HuagongsheHuagongshe Chemistry Print Report · For research reference only
Mercuric cyanide → 3,4,5-trimethoxyphenyl 2,3,4-tri-O-acetyl-1,5-dithio-beta-D-xylopyranoside
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Mercuric cyanide | HCID 11591 | — |
| Reactant | 2,3,4-tri-O-acetyl-5-thio-alpha-xylopyranosyl bromide | HCID 10926314 | — |
| Reactant | 3,4,5-Trimethoxybenzenethiol | HCID 15198240 | — |
| Product | 3,4,5-trimethoxyphenyl 2,3,4-tri-O-acetyl-1,5-dithio-beta-D-xylopyranoside | HCID 14795351 | 28% |
Reaction Steps
If the procedure described in Preparation I is followed starting from 11.35 g (57.10-3 mol) of 3,4,5-trimethoxybenzenethiol, 14.32 g (57.10-3 mol) of mercuric cyanide, Hg(CN)2, and 22.15 g (62.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide, 7.52 g (yield: 28%) of the expected product are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05101048 |
| Source dataset | uspto-grants-1992_03 |
| ORD ID | ord-66d989a956034222a0b61c99e7173eb3 |
| Source note | uspto-grants-1992_03 |