Morpholine → HCID 59855627, compound

HRID 2376599Notes

Reaction equation

HRID 2376599 reaction equation
[NH:1]1[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1.[C:7]([O:11][CH2:12][C:13]([F:24])([F:23])[C:14]([F:22])([F:21])[C:15]([F:20])([F:19])[CH:16]([F:18])[F:17])(=[O:10])[CH:8]=[CH2:9]>>[O:4]1[CH2:5][CH2:6][N:1]([CH2:9][CH2:8][C:7]([O:11][CH2:12][C:13]([F:23])([F:24])[C:14]([F:21])([F:22])[C:15]([F:20])([F:19])[CH:16]([F:17])[F:18])=[O:10])[CH2:2][CH2:3]1

Participants

3

Reactant 2

HCID 8083MorpholineHCID 678291H,1H,5H-Perfluoropentyl acrylate

Product 1

HCID 59855627HCID 59855627, compoundYield 97%

Procedure

With ice cooling and stirring, 9.6 g of morpholine was added dropwise to 28.6 g of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate. The mixture was stirred for one hour at room temperature, after which it was directly distilled for purification. There was obtained 36.2 g of 2,2,3,3,4,4,5,5-octafluoropentyl 3-morpholinopropionate (boiling point 84° C./13 Pa, yield 97%).

Workup

  1. stirringThe mixture was stirred for one hour at room temperature
  2. distillationafter which it was directly distilled for purification

Sources & evidence

ORD record
ord-ed3846141c464434b958c642eced1352
Source dataset
uspto-grants-2008_12
Patent number
US07468236B2

Reaction notes

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