Lithium Hydroxide → HCID 69197921, compound

HRID 2376797Notes

Reaction equation

C[O:2][C:3](=[O:22])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]1[CH2:13][CH:12]1[CH2:14]/[CH:15]=[CH:16]\[CH2:17][CH2:18][CH2:19][CH2:20][CH3:21].[OH-].[Li+]>>[CH2:14]([CH:12]1[CH2:13][CH:11]1[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][C:3]([OH:22])=[O:2])/[CH:15]=[CH:16]\[CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]

Participants

Reactant 2

HCID 3939Lithium Hydroxide

HCID 69201087HCID 69201087, compound

Product 1

HCID 69197921HCID 69197921, compound

Procedure

In the same manner as in Example 1(2) using 8-(2-(2-(Z)-octenyl)cyclopropyl)octanoic acid methyl ester and 0.5N lithium hydroxide instead of 1N lithium hydroxide, 8-(2-(2-(Z)-octenyl)cyclopropyl)octanoic acid was obtained as an oil (56.3 mg).

Sources & evidence

ORD record: ord-944335cb4aaf47369bf401d0b5e1053e
Source dataset: uspto-grants-2008_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07468389B2

Reaction notes

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