Acetone → HCID 11070066, compound

HRID 2379497Notes

Reaction equation

[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([C:17]2[CH:22]=[CH:21][C:20]([OH:23])=[CH:19][CH:18]=2)([C:10]2[CH:15]=[CH:14][C:13]([OH:16])=[CH:12][CH:11]=2)[CH3:9])=[CH:4][CH:3]=1.C(O[C:28](=[O:30])[CH3:29])(=O)C.[2H]C([C:35]([C:37]([2H])([2H])[2H])=[O:36])([2H])[2H].[CH3:41][C:42](C)=[O:43]>>[C:42]([O:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([C:10]2[CH:15]=[CH:14][C:13]([O:16][C:28](=[O:30])[CH3:29])=[CH:12][CH:11]=2)([C:17]2[CH:18]=[CH:19][C:20]([O:23][C:35](=[O:36])[CH3:37])=[CH:21][CH:22]=2)[CH3:9])=[CH:4][CH:3]=1)(=[O:43])[CH3:41]

Participants

Reactant 4

HCID 180Acetone

HCID 7918Acetic Anhydride

HCID 931181,1,1-Tris(4-hydroxyphenyl)ethane

HCID 522220Acetone-D6

Product 1

HCID 11070066HCID 11070066, compoundYield 97%

Procedure

1,1,1-Tris(4-hydroxyphenyl)ethane was acetylated with acetic anhydride as in the example above. A white solid was obtained in 97% yield, MP=169° C. NMR (1H, d-6 acetone)--7.06(q), 2.28(s), 2.24(s), 13C NMR (d-6 acetone)--169.65, 149, 146.19, 129.75, 120.98, 51.45, 30.61, 20.91.

Workup

customA white solid was obtained in 97% yield, MP=169° C

Sources & evidence

ORD record: ord-df34ef33f6184a0aaa3e0c36bcb26e90
Source dataset: uspto-grants-1994_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05362843

Reaction notes

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