Thionyl Chloride → 4'-Decyloxybiphenyl-4-carboxylic acid chloride

HRID 2379650Notes

Reaction equation

HRID 2379650 reaction equation
[CH2:1]([O:11][C:12]1[CH:17]=[CH:16][C:15]([C:18]2[CH:23]=[CH:22][C:21]([C:24]([OH:26])=O)=[CH:20][CH:19]=2)=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].S(Cl)([Cl:29])=O>>[CH2:1]([O:11][C:12]1[CH:17]=[CH:16][C:15]([C:18]2[CH:23]=[CH:22][C:21]([C:24]([Cl:29])=[O:26])=[CH:20][CH:19]=2)=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

3

Reactant 2

HCID 24386Thionyl ChlorideHCID 114510854'-Decyloxybiphenyl-4-carboxylic Acid

Product 1

HCID 140699444'-Decyloxybiphenyl-4-carboxylic acid chloride

Procedure

4'-n-Decyloxy-4-carboxybiphenyl (3.00 g) was heated under reflux for 6 hours together with an excessive amount of thionyl chloride, and the unaltered thionyl chloride was removed by distillation to give about 3 g of 4'-n-decyloxybiphenyl-4-carboxylic acid chloride.

Workup

  1. customthe unaltered thionyl chloride was removed by distillation

Sources & evidence

ORD record
ord-27266cd6d2d84f0f9f4444d5fe196321
Source dataset
uspto-grants-1994_11
Patent number
US05364561

Reaction notes

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