HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyl dicarbonate → HCID 69812006, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyl dicarbonate | HCID 3086 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Reactant | 4-(2,2,2-Trifluoro-1-methyl-ethoxy)-aniline | HCID 66277568 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 69812006 | HCID 69812006 | — |
Reaction Steps
This material was prepared from (rac)-4-(2,2,2-trifluoro-1-methyl-ethoxy)-phenylamine by, first an standard methoxycarbonylation reaction with dimethyl dicarbonate in methylene chloride (at RT and 12 h stirring) followed by reduction with LiAlH4 according to standard literature procedures.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08258158B2 |
| Source dataset | uspto-grants-2012_09 |
| ORD ID | ord-d73912abed0543fb9fcad81c6a870449 |
| Source note | uspto-grants-2012_09 |