Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Isopropyltriphenylphosphonium iodide → 3-Bromo-4-(2-methylprop-1-en-1-yl)pyridine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Isopropyltriphenylphosphonium iodide | HCID 2723783 | — |
| 반응물 | 3-Bromopyridine-4-carboxaldehyde | HCID 2762997 | — |
| 반응물 | 3-Bromo-4-(hex-1-en-1-yl)pyridine | HCID 67008079 | — |
| 생성물 | 3-Bromo-4-(2-methylprop-1-en-1-yl)pyridine | HCID 58522086 | — |
반응 단계
Following the general method as outlined in Intermediate 12, starting from 3-bromo-4-pyridinecarboxaldehyde (Aldrich) and isopropyltriphenylphosphonium iodide, the title compound was obtained as a yellow liquid after purification by flash column chromatography, eluting with cyclohexane containing increasing amounts of EtOAc.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08273769B2 |
| 출처 데이터셋 | uspto-grants-2012_09 |
| ORD ID | ord-8e4063fddd9b496180018803958ca9ee |
| 출처 메모 | uspto-grants-2012_09 |