Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Trichlorosilane | HCID 24811 | — |
| Reactant | 3,3,4,4-Tetrafluorohexa-1,5-diene | HCID 74482 | — |
| Catalyst | Platinate(2-), hexachloro-, hydrogen, hydrate (1:2:1), (OC-6-11)- | HCID 16211507 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 58121700 | HCID 58121700 | 96% |
Reaction Steps
1,2-Diethenyltetrafluoroethane (1 g, 6.5 mmol) and 4 mg of hydrogen hexachloroplatinate (IV) hydrate were dissolved in dried CH2Cl2 (15 mL). Trichlorosilane (10 mL, 9.9 mmol) was added dropwise to the stirred solution. The reaction mixture was heated at 40° C. overnight, followed by removal of excess HSiCl3 and solvent by vacuum evaporation. The crude product was recovered in a yield of greater than about 96% (2.6 g). 1H NMR (400 Mz, CDCl3): δ 2.4 (m, 4H), 1.4 (m, 4H). 29Si NMR (CDCl3): 14.1 (s). 19F NMR (CDCl3): −115.1 (t, J=12 Hz, 4F).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US08274075B2 |
|---|
| Source dataset | uspto-grants-2012_09 |
|---|
| ORD ID | ord-c8835bef8f574aa09ca69655a8122dc7 |
|---|
| Source note | uspto-grants-2012_09 |
|---|
