Diethanolamine → HCID 18980528, compound

HRID 2392734Notes

Reaction equation

HRID 2392734 reaction equation
[CH3:1][CH:2]([CH2:19][CH2:20][CH2:21][CH3:22])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][O:14][CH2:15][CH:16]1[O:18][CH2:17]1.[NH:23]([CH2:27][CH2:28][OH:29])[CH2:24][CH2:25][OH:26]>C(O)C>[OH:26][CH2:25][CH2:24][N:23]([CH2:27][CH2:28][OH:29])[CH2:17][CH:16]([OH:18])[CH2:15][O:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH:2]([CH3:1])[CH2:19][CH2:20][CH2:21][CH3:22]

Participants

4

Reactant 2

HCID 8113DiethanolamineHCID 18980524HCID 18980524, compound

Product 1

HCID 18980528HCID 18980528, compoundYield 65.8%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Conditions

Temperature
80 °C

Procedure

In a 10 ml round bottomed flask, 12-methylhexadecylglycidylether (100 mg, 0.32 mmol), diethanolamine (35 mg, 0.33 mmol), and ethanol (1 ml) were placed. The content of the flask was stirred for 1 hour at 80° C. in a nitrogen atmosphere. The mixture was condensed under reduced pressure, and the resulting residue was purified by silica gel flush chromatography. As a result, 88 mg of the title compound was obtained as a pale yellow oil (yield: 66%).

Workup

  1. customcondensed under reduced pressure
  2. customthe resulting residue was purified by silica gel
  3. customflush chromatography

Sources & evidence

ORD record
ord-f606709b6f1448f1b2226a3412cda82c
Source dataset
uspto-grants-1998_09
Patent number
US05801202

Reaction notes

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