HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formaldehyde → HCID 18980511, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formaldehyde | HCID 712 | — |
| Reactant | Dimethylamine, hydrochloride | HCID 10473 | — |
| Reactant | 4-(2-Propen-1-yloxy)cyclohexanone | HCID 18413729 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | HCID 18980511 | HCID 18980511 | 77% |
Reaction Steps
15.5 g of compound (12) (100 mmole), 1.5 g (50 mmole) paraformaldehyde and 4.1 g (50 mmole) dimethylamine hydrochloride were stirred for 25 minutes in 30 ml acetic acid in a bath at 105° C. The acetic acid was distilled off under vacuum, and the residue was dissolved in 110 ml 2-butanone. Compound (13) was obtained in a yield of 77% theoretical, melting point 125° C.-127° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05801201 |
| Source dataset | uspto-grants-1998_09 |
| ORD ID | ord-1795393f293147048d40a651f097c603 |
| Source note | uspto-grants-1998_09 |