Carbon Dioxide → HCID 178527050, compound

HRID 2392843Notes

Reaction equation

HRID 2392843 reaction equation
C(=O)([O-])O.[Na+:5].[C:6]1([P:12]([C:23]2[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=2)[C:13]2[CH:18]=[CH:17][C:16]([CH2:19][PH:20](=[O:22])[OH:21])=[CH:15][CH:14]=2)[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.C(=O)=O>>[C:6]1([P:12]([C:23]2[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=2)[C:13]2[CH:18]=[CH:17][C:16]([CH2:19][PH:20](=[O:21])[O-:22])=[CH:15][CH:14]=2)[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1.[Na+:5]

Participants

4

Reactant 3

HCID 280Carbon DioxideHCID 516892Sodium BicarbonateHCID 178527049HCID 178527049, compound

Product 1

HCID 178527050HCID 178527050, compoundYield 97.6%

Procedure

100 ml of a 3.7% strength by weight sodium hydrogen carbonate solution (44.1 mmol NaHCO3) are added to 15.0 g (44.1 mmol) of (4-diphenylphosphinophenyl)methylphosphinic acid and the mixture stirred at room temperature until CO2 formation has ended. The aqueous solution is completely evaporated and dried under reduced pressure. 15.6 g (97% of theory) of sodium (4-diphenylphosphinophenyl)methylphosphinate are obtained. Solubility in water: 590 g/l

Workup

  1. customThe aqueous solution is completely evaporated
  2. customdried under reduced pressure

Sources & evidence

ORD record
ord-a18b8d5f298b49b6ac6e449fb0b24bea
Source dataset
uspto-grants-1998_09
Patent number
US05801263

Reaction notes

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